Additions of carbenium ions to nonconjugated dienes. The retarding (−I)-effect of the second double bond.

Chemie und Pharmazie - Open Access LMU - Teil 01/02 by Ludwig-Maximilians-Universität München

Kinetics for the addition of the p-methoxybenzhydryl cation (AnPhCH+, 10) towards nonconjugated dienes 11 [H2C=C(CH3)-(CH2)n-C(CH3)=CH2] have been determined in CH2Cl2 at −30° to −70°C. Reactivity increases with increasi...View more